Excerpt from the Lexham Bible Dictionary, the most advanced Bible dictionary.
Also called “Aliah.” Listed among the Edomites, who were descendants of Esau. Alvan be the same person referred to as “Alvah,” an Edomite chief (Gen 36:23, 40; 1 Chr 1:51).
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ALVAN (PERSON) [Heb ʿalwān (עַלְוָן)] Var. ALIAN. A clan name mentioned in the genealogy of Seir the Horite in Gen 36:23. These clans, not to be confused with Hurrian groups in Mesopotamia, are mentioned as the original “inhabitants of the land” of Edom (perhaps as cave dwellers). Alvan is listed as
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ALIAN<a-li’-an> ( עַלְיָן [̀alyan]): A descendant of Esau, and son of Shobal (1 Chronicles 1:40). In the corresponding earlier genealogy (Genesis 36:23) the same person is given as Alvan ( עַלְוָן [̀alwan]), the change of the third consonant being a simple one, common to Hebrew, occurring similarly